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“A few persons are still feared trapped and efforts are on to rescue them,” an NDRF official said.
Three persons were injured in the incident and they were being treated at Chhatrapati Shivaji Maharaj Hospital at Kalva in Thane, he said.
CM Shinde announced an aid of Rs 5 lakh to the families of each of the deceased.
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The accident took place during the third phase work of the Samruddhi Mahamarg, he added.
The Samruddhi Mahamarg, named Hindu Hrudaysamrat Balasaheb Thackeray Maharashtra Samruddhi Mahamarg, is a 701-km-long expressway connecting Mumbai and Nagpur.
It traverses 10 districts including Nagpur, Washim, Wardha, Ahmednagar, Buldhana, Aurangabad, Amravati, Jalna, Nashik and Thane.
The construction of the Samruddhi Mahamarg is being carried out by the Maharashtra State Road Development Corporation.
The first phase, connecting Nagpur to the temple town of Shirdi, was inaugurated by Prime Minister Narendra Modi in December 2022. It covers a distance of 520 km.
CM Shinde and Deputy Chief Minister Devendra Fadnavis inaugurated the 80 km long second phase of the Samruddhi Mahamarg stretch from Bharvir village in Igatpuri taluka to Shirdi on May 26.
Shinde said in May that the third and last phase would be completed by the end of December this year.