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Four others in the vehicle, including the driver, escaped with injuries and their condition was stable as of now, police said.
The deceased were natives of Ayur in Kollam district, they said.
According to eye-witnesses, the incident occurred as the car, moving in high speed, overturned and plunged into the canal near the bypass. The vehicle could be seen swept away for some distance due to strong currents, they said.
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But, three women succumbed to the injuries, they added.