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The accident took place late Sunday night near Gauda Pulia under Palari police station area, located 70 km from the state capital Raipur. The victims, natives of Latua village, were returning after attending a family function in Parsada village, a senior police official said.
Chief Minister Bhupesh Baghel expressed grief over the incident.
The van collided head-on with the truck. Five women and a six-year-old boy died on the spot and 21 others were injured, five of them critically, the police official said.
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CM Baghel expressed grief over the incident and directed the officials to provide best medical assistance to the injured persons.