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The two accused arrived at the home of another person around 2 am on Monday over past enmity but did not find the latter.
The accused then injured the two persons present there with the butt of a revolver. They also fired one round at them though the bullet did not hit anyone, said inspector Pradip Patil of the MFC police station in Kalyan.
A case has been registered under the Indian Penal Code sections, including 307 (attempt to murder), and the Arms Act, he added.