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The incident took place on Tuesday at the police outpost in Wagholi area.
Police personnel put out the flames and rushed the man, identified as Rohidas Jadhav, to a hospital. He is in a critical condition, the police said.
Jadhav had lodged a complaint against another person over a parking dispute in his housing society, and police had registered a non-cognisable (NC) offence. A counter-complaint was also lodged.
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Jadhav, however, was not convinced. He went out and set himself on fire after dousing himself with some inflammable substance, he said.