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More than 70 others were rescued from the unit, located in Kadodara industrial area, they said, adding that some workers were also injured in the incident.
The rescue operation was still underway, officials said.
The blaze erupted in the Viva Packaging Company at around 4.30 am, Kadodara police inspector Hemant Patel said.
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Hydraulic cranes were used to rescue workers trapped inside the building, he said.
The cause of the fire was yet to be ascertained, officials said.