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The aircraft is expected to bring back Indians from Romania, who exited war-hit Ukraine through its border crossings.
Officials said the aircraft left for Romania early morning.
India on Tuesday sent the first tranche of humanitarian assistance comprising medicines and other relief materials to Ukraine via Poland.
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”The prime minister noted that the first consignment of relief supplies to Ukraine to deal with the humanitarian situation on Ukraine’s borders would be despatched tomorrow,” the Ministry of External Affairs said on Monday.