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After Australia lost dependable opener Alyssa Healy for 18, Mooney, who had struck 54 against India in the semifinal against India, did the rebuilding work with Ashleigh Gardner (29).
The in-form batter smashed nine boundaries and a six at a strike rate of nearly 140 to trouble the Proteas bowlers.
Healy was undone by a short ball with extra bounce. The veteran opener could not get going as she tried to heave the ball over cover only to be caught by Nadine De Klerk off Marizanne Kapp.
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Brief Scores: Australia: 156 for 6 in 20 overs (Beth Mooney 74, Ashleigh Gardner 29; Marizanne Kapp 2/35).