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The unseeded Indo-Ukrainian team may run into Spanish fourth seeds Georgina Garcia Perez and Sara Sorribes Tormo in the quarterfinals.
The Spanish players had reached three WTA tour finals in 2019 season and won two of them.
Sania is returning to the circuit after two years, having started a family with Pakistan cricketer Shoaib Malik.
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Bopanna began the season in splendid fashion winning the ATP Qatar Open with Wesley Koolhof.
Last year also Bopanna had begun with a title win in Pune with Jeevan Nedunchezhiyan.