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South Africa still trail India by 252 runs with six wickets in hand.
At the break, Temba Bavuma (2 not out) and Quinton de Kock (1 not out) were at the crease.
For India, Ravichandran Ashwin (2/8) picked up two wickets so far.
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India 1st innings: 601 for 5 declared
South Africa 1st innings: 275 all out & 74 for 4 in 27 overs (dean Elgar 48; Ravichandran Ashwin 2/8).