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Five Central Reserve Police Force (CRPF) jawans also received injuries in the mishap, he said.
Ahir escaped unhurt as he was not in the ill-fated vehicle, he said.
The former minister was heading towards Nagpur along with his security convoy in four vehicles when the mishap took place at Jam village on Chandrapur-Nagpur road, around 233 km from here.
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CRPF jawan Phalji Patel and the vehicle driver Vinod Zade received serious injuries in the mishap and were rushed to a hospital where they died while undergoing treatment, Ahir’s personal assistant Ravi Chawre said.
The five other injured CRPF jawans were admitted to the Orange City Hospital in Nagpur, he added.