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In the 40-shot final, the 46-year-old from Uttar Pradesh shot 37 to finish ahead of Korea’s Minsu Kim (36) and Britain’s Ben Llewellin (26), who won the silver and bronze respectively.
The shooter shot 119/125 over two days of qualifying before coming through in a five-way shoot-off enroute his maiden individual gold.
The two-time Olympian, who is the oldest member of the Indian contingent in Changwon this year, had won a silver at the 2016 World Cup in Rio de Janeiro.
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The Indians outplayed the Austrian team of Sheileen Waibel, Nadine Ungerank, and Rebecca Koeck 16-6 in the bronze medal match to comfortably secure a podium finish.
But the day undoubtedly belonged to Khan. After finishing with 119, he found himself vying for two final qualification spots along with four others, including two-time Olympic medallist Abdullah Al Rashidi of Kuwait. When Shotaro Toguchi of Japan missed his eighth shoot-off shot, he was assured of a top-eight spot.
In the ranking round he was up against German Sven Korte, Korean Minki Cho and Cypriot Nicolas Vasilou for another round of 30 targets. He topped the round with 27 hits as Sven followed him to the medal round with 25 hits.
In other results, Vijayveer Sidhu made the ranking round but failed to advance to the medal rounds while Anish and Sameer could not cross the first hurdle in the men’s 25m rapid fire pistol.
Vijayveer shot 584 in qualifying to finish sixth while Anish shot 582 for the 12th spot and Sameer 566 for the 30th position.
Mufaddal Deesawala finished 23rd in the women’s skeet shooting a total of 108.
With one gold and bronze on Monday, India remained on top of the medal tally with 13 podiums (5 gold, 5 silver, and 3 bronze).